Borate nitrate

Borate nitrates are mixed anion compounds containing separate borate and nitrate anions.

List

	chem	mw	crystal system	space group	unit cell Å	volume	density	comment	references
	Na₃(NO₃)[B₆O₁₀]								^[1]
	K₃B₆O₁₀NO₃								^[2]
	K₃Na[B₆O₉(OH)₃]NO₃			Pnnm	a=13.208, b=9.107, c=12.325 Z=4				^[3]
	Co₃B₇O₁₃NO₃								^[4]
	[Co(H₂O)₆](NO₃)₂·[Co{B₃O₃(OH)₄}₂(H₂O)₄]·2H₂O								^[5]
	[Ni(H₂O)₆](NO₃)₂·[Ni{B₃O₃(OH)₄}₂(H₂O)₄]·2H₂O								^[5]
	Ni₃B₇O₁₃NO₃								^[4]
	K₇Ni[B₁₈O₂₄(OH)₉](NO₃)₆· (H₃BO₃)	1497.96	trigonal	R3	a=12.2229 c=54.784 Z=6	7088	2.11	green	^[6]
	Cu₃B₇O₁₃NO₃								^[4]
	Zn₃B₇O₁₃NO₃								^[4]
	[Zn(H₂O)₆](NO₃)₂·[Zn{B₃O₃(OH)₄}₂(H₂O)₄]·2H₂O		monoclinic	P2₁/c	a = 11.282, b = 6.5374, c = 17.668, β = 100.981°				^[5]
	Rb₃(NO₃)[B₆O₁₀]								^[2]
	Ag₁₂(B₉O₁₈)(NO₃)₃		hexagonal	P6₃/m	a = 11.2896 c = 11.6693				^[7]
	Cd₃B₇O₁₃NO₃								^[4]
	La[B₅O₈(OH)]NO₃
	La[B₅O₈(OH)]NO₃·2H₂O		monoclinic	P2₁/n	a=6.540, b=15.550, c=10.672, β=90.44° and Z=4				^[8]
cerium(III) aquahydroxidooctaoxidopentaborate nitrate dihydrate	Ce[B₅O₈(OH)(H₂O)]NO₃·2H₂O	455.24	monoclinic	P2₁/n	a=6.444 b=15.572 c=10.745 β=90.395 Z=4	1078.2	2.904	colourless	^[9]
	Pr[B₅O₈(OH)(H₂O)_x]NO₃·2H₂O		monoclinic	P2₁/n	a=6.419, b=15.518, c=10.684, with β=90.54° Z=4	1064.3			^[10]
	Pr₇(BO₃)₃(NO₃)N₃O		hexagonal	P6₃	a=10.6834 c=6.6752 Z=2		6.457	green; contains N(OBO₃)₃ clusters, oxide and nitride	^[11]
	Nd₇(BO₃)₃(NO₃)N₃O		hexagonal	P6₃	a=10.6446 c=6.6339 Z=2		6.664	purplish-blue;contains N(OBO₃)₃ clusters oxide, and nitride;SHG	^[11]
	Nd[B₅O₈(OH)(H₂O)_x]NO₃·2H₂O			P2₁/n	a = 6.4285, b = 15.5258, c = 10.7052, β = 90.39°	1068.44			^[12]
	Sm[B₅O₈(OH)(H₂O)_x]NO₃·2H₂O			P2₁/n	a = 6.4409, b = 15.4199, c = 10.5097, β = 90.33°	1043.79			^[12]
	Lu₂B₂O₅(NO₃)₂·2H₂O		triclinic	P1	a=7.8952, b=9.8862, c=14.6033, α=90.83, β=101.75, γ=110.02° Z=4				^[6]^[13]
	Pb₂(BO₃)(NO₃)	535.20	hexagonal	P6₃mc	a=5.0731 c=13.040 Z=2	290.64	6.116	colourless SHG 9×KDP	^[14]
	[Pb₃(B₃O₇)](NO₃)	828.01		Pnma	a=10.3481 b=7.8908 c=11.2123 Z=4	914.54	6.007	colourless	^[15]

References

^ Ortner, Teresa S.; Schildhammer, Daniel; Tribus, Martina; Joachim, Bastian; Huppertz, Hubert (2017-03-01). "Synthesis and characterization of the alkali borate-nitrates Na3–x Kx[B6O10]NO3 (x=0.5, 0.6, 0.7)". Zeitschrift für Naturforschung B. 72 (3): 215–223. doi:10.1515/znb-2016-0242. ISSN 1865-7117. S2CID 99165997.
^ ^a ^b Zhang, Qiqi; Zhang, Fangfang; Li, Fuming; Han, Shujuan; Yang, Zhihua; Pan, Shilie (2021-02-13). "M3B6O10NO3 (M = K, Rb): Two new alkali metal borate-nitrates with noncentrosymmetric structures". European Journal of Inorganic Chemistry. 2021 (13): 1297–1304. doi:10.1002/ejic.202001167. ISSN 1434-1948. S2CID 233784768.
^ Ortner, Teresa S.; Wurst, Klaus; Perfler, Lukas; Tribus, Martina; Huppertz, Hubert (January 2015). "Hydrothermal synthesis and characterization of the first mixed alkali borate-nitrate K3Na[B6O9(OH)3]NO3". Journal of Solid State Chemistry. 221: 66–72. Bibcode:2015JSSCh.221...66O. doi:10.1016/j.jssc.2014.09.016.
^ ^a ^b ^c ^d ^e Bither, Tom A.; Young, Howard S. (1974-08-01). "Nitrato- and fluoroboracites M3B7O13NO3 and M3B7O13F". Journal of Solid State Chemistry. 10 (4): 302–311. Bibcode:1974JSSCh..10..302B. doi:10.1016/0022-4596(74)90039-5. ISSN 0022-4596.
^ ^a ^b ^c Liu, Ying; Deng, Jun-Xia; Pan, Chun-Yang (2020-05-04). "Synthesis and Structural Manipulation of a Polyanionic Zincoborate [Zn(H2O)6](NO3)2·[Zn{B3O3(OH)4}2(H2O)4]·2H2O by the Molten Salt Method and its Potential Application as a Flame Retardant". Journal of Cluster Science. 32 (2): 469–477. doi:10.1007/s10876-020-01806-7. ISSN 1040-7278. S2CID 218495402.
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